Title:
A polychloride-enabled synthesis of [NEt3Me][PCl6] serving as a potential PCl3-storage and PCl5-reagent†
Author(s):
Ernst, Moritz J.; Kleoff, Merlin; Voßnacker, Patrick; Thiele, Günther; Müller, Christian; Riedel, Sebastian
Year of publication:
2024
Available Date:
2024-11-13T11:16:47Z
Abstract:
Reaction of the ionic liquid [NEt3Me][Cl3] with white phosphorus (P4) gives, quantitatively, hexachlorophosphate [NEt3Me][PCl6]. This compound shows similar reactivity as PCl5, as confirmed for the reaction with phenol, carboxylic acids and ammonium chloride. At elevated temperature, [NEt3Me][PCl6] releases PCl3 and can therefore be used as a potential PCl3-storage material.
Part of Identifier:
ISSN (print): 1359-7345
e-ISSN (online): 1364-548X
Keywords:
polychloride-enabled synthesis
PCl3-storage
PCl5-reagent
DDC-Classification:
540 Chemie und zugeordnete Wissenschaften
Publication Type:
Wissenschaftlicher Artikel
URL of the Original Publication:
DOI of the Original Publication:
Journaltitle:
Chemical Communications
Department/institution:
Biologie, Chemie, Pharmazie
Institut für Chemie und Biochemie
