dc.contributor.author
Ernst, Moritz J.
dc.contributor.author
Kleoff, Merlin
dc.contributor.author
Voßnacker, Patrick
dc.contributor.author
Thiele, Günther
dc.contributor.author
Müller, Christian
dc.contributor.author
Riedel, Sebastian
dc.date.accessioned
2024-11-13T11:16:47Z
dc.date.available
2024-11-13T11:16:47Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/45644
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-45357
dc.description.abstract
Reaction of the ionic liquid [NEt3Me][Cl3] with white phosphorus (P4) gives, quantitatively, hexachlorophosphate [NEt3Me][PCl6]. This compound shows similar reactivity as PCl5, as confirmed for the reaction with phenol, carboxylic acids and ammonium chloride. At elevated temperature, [NEt3Me][PCl6] releases PCl3 and can therefore be used as a potential PCl3-storage material.
en
dc.format.extent
4 Seiten
dc.rights.uri
https://creativecommons.org/licenses/by/4.0/
dc.subject
polychloride-enabled synthesis
en
dc.subject
PCl3-storage
en
dc.subject
PCl5-reagent
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::540 Chemie und zugeordnete Wissenschaften
dc.title
A polychloride-enabled synthesis of [NEt3Me][PCl6] serving as a potential PCl3-storage and PCl5-reagent†
dc.type
Wissenschaftlicher Artikel
dc.date.updated
2024-11-13T03:50:56Z
dcterms.bibliographicCitation.doi
10.1039/d4cc04319g
dcterms.bibliographicCitation.journaltitle
Chemical Communications
dcterms.bibliographicCitation.number
91
dcterms.bibliographicCitation.pagestart
13372
dcterms.bibliographicCitation.pageend
13375
dcterms.bibliographicCitation.volume
60
dcterms.bibliographicCitation.url
https://doi.org/10.1039/D4CC04319G
refubium.affiliation
Biologie, Chemie, Pharmazie
refubium.affiliation.other
Institut für Chemie und Biochemie
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.issn
1359-7345
dcterms.isPartOf.eissn
1364-548X
refubium.resourceType.provider
DeepGreen
