Title:
Highly flexible phosphabenzenes: a missing coordination mode of 2,4,6-triaryl-λ3-phosphinines
Author(s):
Yue, Erlin; Petrov, Andrey; Frost, Daniel S.; Dettling, Lea; Conrad, Lawrence; Wossidlo, Friedrich; Coles, Nathan T.; Weber, Manuela; Müller, Christian
Year of publication:
2022
Available Date:
2022-05-27T09:53:17Z
Abstract:
The reaction of 2,4,6-triaryl-λ3-phosphinine-Cr(CO)3-π-complexes with [Rh(COD)2]BF4 leads to unusual diamagnetic Rh0-dimers, which contain two phosphinine-π-complexes acting as a bridging 2e−-ligand towards the Rh2(CO)2 core. These compounds represent a missing coordination mode for the aromatic 6-membered phosphorus heterocycle.
Part of Identifier:
e-ISSN (online): 1364-548X
Keywords:
phosphabenzenes
missing coordination mode
aromatic 6-membered phosphorus heterocycle
DDC-Classification:
540 Chemie und zugeordnete Wissenschaften
Publication Type:
Wissenschaftlicher Artikel
URL of the Original Publication:
DOI of the Original Publication:
Journaltitle:
Chemical Communications
Department/institution:
Biologie, Chemie, Pharmazie
Institut für Chemie und Biochemie
