dc.contributor.author
Yue, Erlin
dc.contributor.author
Petrov, Andrey
dc.contributor.author
Frost, Daniel S.
dc.contributor.author
Dettling, Lea
dc.contributor.author
Conrad, Lawrence
dc.contributor.author
Wossidlo, Friedrich
dc.contributor.author
Coles, Nathan T.
dc.contributor.author
Weber, Manuela
dc.contributor.author
Müller, Christian
dc.date.accessioned
2022-05-27T09:53:17Z
dc.date.available
2022-05-27T09:53:17Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/35064
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-34781
dc.description.abstract
The reaction of 2,4,6-triaryl-λ3-phosphinine-Cr(CO)3-π-complexes with [Rh(COD)2]BF4 leads to unusual diamagnetic Rh0-dimers, which contain two phosphinine-π-complexes acting as a bridging 2e−-ligand towards the Rh2(CO)2 core. These compounds represent a missing coordination mode for the aromatic 6-membered phosphorus heterocycle.
en
dc.format.extent
4 Seiten
dc.rights.uri
https://creativecommons.org/licenses/by-nc/4.0/
dc.subject
phosphabenzenes
en
dc.subject
missing coordination mode
en
dc.subject
aromatic 6-membered phosphorus heterocycle
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::540 Chemie und zugeordnete Wissenschaften
dc.title
Highly flexible phosphabenzenes: a missing coordination mode of 2,4,6-triaryl-λ3-phosphinines
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.doi
10.1039/D2CC01817A
dcterms.bibliographicCitation.journaltitle
Chemical Communications
dcterms.bibliographicCitation.number
42
dcterms.bibliographicCitation.pagestart
6184
dcterms.bibliographicCitation.pageend
6187
dcterms.bibliographicCitation.volume
58
dcterms.bibliographicCitation.url
https://doi.org/10.1039/D2CC01817A
refubium.affiliation
Biologie, Chemie, Pharmazie
refubium.affiliation.other
Institut für Chemie und Biochemie
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.eissn
1364-548X
refubium.resourceType.provider
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