A new retrieval of total column water vapour (TCWV) from daytime measurements over land of the Ocean and Land Colour Instrument (OLCI) on-board the Copernicus Sentinel-3 missions is presented. The Copernicus Sentinel-3 OLCI Water Vapour product (COWa) retrieval algorithm is based on the differential absorption technique, relating TCWV to the radiance ratio of non-absorbing band and nearby water vapour absorbing band and was previously also successfully applied to other passive imagers Medium Resolution Imaging Spectrometer (MERIS) and Moderate Resolution Imaging Spectroradiometer (MODIS). One of the main advantages of the OLCI instrument regarding improved TCWV retrievals lies in the use of more than one absorbing band. Furthermore, the COWa retrieval algorithm is based on the full Optimal Estimation (OE) method, providing pixel-based uncertainty estimates, and transferable to other Near-Infrared (NIR) based TCWV observations. Three independent global TCWV data sets, i.e., Aerosol Robotic Network (AERONET), Atmospheric Radiation Measurement (ARM) and U.S. SuomiNet, and a German Global Navigation Satellite System (GNSS) TCWV data set, all obtained from ground-based observations, serve as reference data sets for the validation. Comparisons show an overall good agreement, with absolute biases between 0.07 and 1.31 kg/m2 and root mean square errors (RMSE) between 1.35 and 3.26 kg/m2. This is a clear improvement in comparison to the operational OLCI TCWV Level 2 product, for which the bias and RMSEs range between 1.10 and 2.55 kg/m2 and 2.08 and 3.70 kg/m2, respectively. A first evaluation of pixel-based uncertainties indicates good estimated uncertainties for lower retrieval errors, while the uncertainties seem to be overestimated for higher retrieval errors.
