In this paper we study a system of decoupled forward-backward stochastic differential equations driven by a G-Brownian motion (G-FBSDEs) with non-degenerate diffusion. Our objective is to establish the existence of a relaxed optimal control for a non-smooth stochastic optimal control problem. The latter is given in terms of a decoupled G-FBSDE. The cost functional is the solution of the backward stochastic differential equation at the initial time. The key idea to establish existence of a relaxed optimal control is to replace the original control problem by a suitably regularised problem with mollified coefficients, prove the existence of a relaxed control, and then pass to the limit.