dc.contributor.author
Rodrigues, Jéssica F.
dc.contributor.author
Londero, Ana Júlia Z.
dc.contributor.author
Tirloni, Bárbara
dc.contributor.author
Roca Jungfer, Maximilian
dc.contributor.author
Abram, Ulrich
dc.contributor.author
Lang, Ernesto S.
dc.date.accessioned
2024-09-11T05:57:04Z
dc.date.available
2024-09-11T05:57:04Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/44712
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-44423
dc.description.abstract
Hydrolysis of PhTeI3 in the presence of sodium phenylseleninate and M3+ ions (M = Y, Nd, Ce) gives well-defined, bowl-shaped telluroxane clusters. Each of the two half-spheres of the compositions [(PhTe)18{ML}O24]7+/8+ ({ML} = {Y(NO3)(H2O)}2+ (1), {Nd(NO3)(H2O)2+} (2), or {Ce(NO3)2}+ (3)) are connected by two (compound 3) or four (compounds 1 and 2) PhSeO2– bridges. The resulting chalcogenoxane spheres have internal volumes of approximately 1500 Å3. Charge compensation is provided by nitrate ions and/or [Na2(NO3)8]6– clusters, which are located inside and surrounding these spheres.
en
dc.format.extent
5 Seiten
dc.rights.uri
https://creativecommons.org/licenses/by/4.0/
dc.subject
Cluster chemistry
en
dc.subject
Cluster ions
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::540 Chemie und zugeordnete Wissenschaften
dc.title
Phenylseleninate-Connected Telluroxane Clusters
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.doi
10.1021/acs.inorgchem.4c02274
dcterms.bibliographicCitation.journaltitle
Inorganic Chemistry
dcterms.bibliographicCitation.number
36
dcterms.bibliographicCitation.pagestart
16590
dcterms.bibliographicCitation.pageend
16594
dcterms.bibliographicCitation.volume
63
dcterms.bibliographicCitation.url
https://doi.org/10.1021/acs.inorgchem.4c02274
refubium.affiliation
Biologie, Chemie, Pharmazie
refubium.affiliation.other
Institut für Chemie und Biochemie
refubium.funding
ACS Publications
refubium.note.author
Die Publikation wurde aus Open Access Publikationsgeldern der Freien Universität Berlin gefördert.
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.eissn
1520-510X
