Title:
Substitution Lability of the Perfluorinated Cp* Ligand in [Rh(COD)(C5(CF3)5)] towards Triphenylpnictogens EPh3 (E = N, P, As, Sb, Bi)
Author(s):
Kub, Nico G.; Sievers, Robin; Parche, Joshua; Malischewski, Moritz
Year of publication:
2024
Available Date:
2024-05-06T06:56:26Z
Abstract:
Triphenylpnictogens EPh3 (E = N, P, As, Sb, Bi) are able to displace the perfluorinated Cp* ligand in [Rh(COD)(C5(CF3)5)] (COD = 1,5-cyclooctadiene) in up to quantitative yield. The resulting ionic products contain [C5(CF3)5]− as uncoordinated counter anion. The cations feature [Rh(COD)]+ fragments, coordinated by one (N, Bi), two (P, As) or three (Sb) triphenylpnictogen moieties. Whereas coordination via the pnictogen is observed for P, As and Sb, π-coordination of the aryl rings is observed for N and Bi.
Part of Identifier:
e-ISSN (online): 1521-3765
Keywords:
cyclopentadienyl ligands
fluorinated ligands
rhodium
pnictogens
arene ligands
DDC-Classification:
540 Chemie und zugeordnete Wissenschaften
Publication Type:
Wissenschaftlicher Artikel
URL of the Original Publication:
DOI of the Original Publication:
Journaltitle:
Chemistry – A European Journal
Department/institution:
Biologie, Chemie, Pharmazie
Institut für Chemie und Biochemie
Comments:
Die Publikation wurde aus Open Access Publikationsgeldern der Freien Universität Berlin gefördert.
