dc.contributor.author
Kub, Nico G.
dc.contributor.author
Sievers, Robin
dc.contributor.author
Parche, Joshua
dc.contributor.author
Malischewski, Moritz
dc.date.accessioned
2024-05-06T06:56:26Z
dc.date.available
2024-05-06T06:56:26Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/42602
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-42326
dc.description.abstract
Triphenylpnictogens EPh3 (E = N, P, As, Sb, Bi) are able to displace the perfluorinated Cp* ligand in [Rh(COD)(C5(CF3)5)] (COD = 1,5-cyclooctadiene) in up to quantitative yield. The resulting ionic products contain [C5(CF3)5]− as uncoordinated counter anion. The cations feature [Rh(COD)]+ fragments, coordinated by one (N, Bi), two (P, As) or three (Sb) triphenylpnictogen moieties. Whereas coordination via the pnictogen is observed for P, As and Sb, π-coordination of the aryl rings is observed for N and Bi.
en
dc.format.extent
6 Seiten
dc.rights.uri
https://creativecommons.org/licenses/by/4.0/
dc.subject
cyclopentadienyl ligands
en
dc.subject
fluorinated ligands
en
dc.subject
arene ligands
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::540 Chemie und zugeordnete Wissenschaften
dc.title
Substitution Lability of the Perfluorinated Cp* Ligand in [Rh(COD)(C5(CF3)5)] towards Triphenylpnictogens EPh3 (E = N, P, As, Sb, Bi)
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.articlenumber
e202400427
dcterms.bibliographicCitation.doi
10.1002/chem.202400427
dcterms.bibliographicCitation.journaltitle
Chemistry – A European Journal
dcterms.bibliographicCitation.number
23
dcterms.bibliographicCitation.volume
30
dcterms.bibliographicCitation.url
https://doi.org/10.1002/chem.202400427
refubium.affiliation
Biologie, Chemie, Pharmazie
refubium.affiliation.other
Institut für Chemie und Biochemie
refubium.funding
DEAL Wiley
refubium.note.author
Die Publikation wurde aus Open Access Publikationsgeldern der Freien Universität Berlin gefördert.
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.eissn
1521-3765
