dc.contributor.author
Görlich, Tim
dc.date.accessioned
2023-06-05T08:12:37Z
dc.date.available
2023-06-05T08:12:37Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/39613
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-39331
dc.description.abstract
The history of the cyaphide anion and all literature known preparations are reviewed. Furthermore, new theoretical insights to the cyaphide ion are presented and complemented with additional calculations. Moreover, several novel cyaphido complexes synthesized by two innovative preparation protocols are demonstrated. The first method takes advantage of a light induced C(sp2)-C(sp) cleavage reaction in a platinum(0) coordinated arylphosphaalkyne to generate the cyaphido ligand. The second method introduces the well-known trimethylsilylphosphaalkyne as cyaphide anion transfer reagent by fluorodesilylation to build new cyaphido gold(I) complexes. Finally, the reactivity of the cyaphido complexes were investigated towards consecutive reactions on the cyaphido moiety, especially by means of [3+2] cycloaddition reactions with organic azides to yield the corresponding triazaphospholato complexes.
en
dc.format.extent
XII, 289 Seiten
dc.rights.uri
http://www.fu-berlin.de/sites/refubium/rechtliches/Nutzungsbedingungen
dc.subject
coordination chemistry
en
dc.subject
cyaphide ion
en
dc.subject
photochemical activation
en
dc.subject
phosphaalkyne
en
dc.subject
addition reaction
en
dc.subject
triazaphosphole
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::546 Anorganische Chemie
dc.title
New synthetic pathways towards cyaphido complexes
dc.contributor.gender
male
dc.contributor.inspector
Schalley, Christoph
dc.contributor.inspector
Rühl, Eckart
dc.contributor.firstReferee
Müller, Christian
dc.contributor.furtherReferee
Hasenstab-Riedel, Sebastian
dc.date.accepted
2023-04-28
dc.identifier.urn
urn:nbn:de:kobv:188-refubium-39613-6
refubium.affiliation
Biologie, Chemie, Pharmazie
dcterms.accessRights.dnb
free
dcterms.accessRights.openaire
open access