dc.contributor.author
Lorente, Alejandro
dc.contributor.author
Ochoa, Andres
dc.contributor.author
Rodriguez-Lavado, Julio
dc.contributor.author
Rodriguez-Nuévalos, Silvia
dc.contributor.author
Jaque, Pablo
dc.contributor.author
Gil, Salvador
dc.contributor.author
Sáez, José A.
dc.contributor.author
Costero, Ana M.
dc.date.accessioned
2023-02-17T14:36:18Z
dc.date.available
2023-02-17T14:36:18Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/37975
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-37691
dc.description.abstract
A new selective fluorogenic chemosensor for Hg2+, which combines a calixarene derivative with a BODIPY core as a fluorescent reporter, is described. The remarkable change in its fluorogenic properties in DMSO and CHCl3 has been analyzed. A study of its spectral properties on dilution, along with molecular modeling studies, allowed us to explain that this behavior involves the formation of a J-dimer, as well as how the sensing mechanism of Hg2+ proceeds.
en
dc.format.extent
10 Seiten
dc.rights.uri
https://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject
Fluorescence
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::540 Chemie und zugeordnete Wissenschaften
dc.title
Unconventional OFF–ON Response of a Mono(calix[4]arene)-Substituted BODIPY Sensor for Hg2+ through Dimerization Reversion
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.doi
10.1021/acsomega.2c06161
dcterms.bibliographicCitation.journaltitle
ACS Omega
dcterms.bibliographicCitation.number
1
dcterms.bibliographicCitation.pagestart
819
dcterms.bibliographicCitation.pageend
828
dcterms.bibliographicCitation.volume
8
dcterms.bibliographicCitation.url
https://doi.org/10.1021/acsomega.2c06161
refubium.affiliation
Biologie, Chemie, Pharmazie
refubium.affiliation.other
Institut für Chemie und Biochemie
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.eissn
2470-1343
refubium.resourceType.provider
WoS-Alert
