Title:
Heterogeneity of oxygen reactivity: key for selectivity of partial methanol oxidation on gold surfaces
Author(s):
Feldt, Christoph D.; Albrecht, Paul Anton; Eltayeb, Salma; Riedel, Wiebke; Risse, Thomas
Year of publication:
2022
Available Date:
2022-05-02T08:10:16Z
Abstract:
Recent evidence for low-temperature oxidation of methyl formate on Au(332) may affect the selectivity of gold catalysts during partial oxidation of methanol. Under isothermal conditions, overoxidation of methyl formate is significantly slower than methanol oxidation which can be attributed to special oxygen species required for overoxidation.
Part of Identifier:
e-ISSN (online): 1364-548X
Keywords:
oxygen reactivity
partial methanol oxidation
gold surfaces
DDC-Classification:
540 Chemie und zugeordnete Wissenschaften
Publication Type:
Wissenschaftlicher Artikel
URL of the Original Publication:
DOI of the Original Publication:
Journaltitle:
Chemical Communications
Department/institution:
Biologie, Chemie, Pharmazie
Institut für Chemie und Biochemie
