dc.contributor.author
Chiesa, A.
dc.contributor.author
Chizzini, M.
dc.contributor.author
Garlatti, E.
dc.contributor.author
Salvadori, E.
dc.contributor.author
Tacchino, F.
dc.contributor.author
Santini, P.
dc.contributor.author
Tavernelli, I.
dc.contributor.author
Bittl, Robert
dc.contributor.author
Chiesa, M.
dc.contributor.author
Sessoli, R.
dc.date.accessioned
2021-09-10T12:31:21Z
dc.date.available
2021-09-10T12:31:21Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/31927
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-31658
dc.description.abstract
Understanding chiral-induced spin selectivity (CISS), resulting from charge transport through helical systems, has recently inspired many experimental and theoretical efforts but is still the object of intense debate. In order to assess the nature of CISS, we propose to focus on electron-transfer processes occurring at the single-molecule level. We design simple magnetic resonance experiments, exploiting a qubit as a highly sensitive and coherent magnetic sensor, to provide clear signatures of the acceptor polarization. Moreover, we show that information could even be obtained from time-resolved electron paramagnetic resonance experiments on a randomly oriented solution of molecules. The proposed experiments will unveil the role of chiral linkers in electron transfer and could also be exploited for quantum computing applications.
en
dc.format.extent
7 Seiten
dc.rights.uri
https://creativecommons.org/licenses/by/4.0/
dc.subject
Charge transfer
en
dc.subject
Electron paramagnetic resonance spectroscopy
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::540 Chemie und zugeordnete Wissenschaften
dc.title
Assessing the Nature of Chiral-Induced Spin Selectivity by Magnetic Resonance
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.doi
10.1021/acs.jpclett.1c01447
dcterms.bibliographicCitation.journaltitle
The Journal of Physical Chemistry Letters
dcterms.bibliographicCitation.number
27
dcterms.bibliographicCitation.pagestart
6341
dcterms.bibliographicCitation.pageend
6347
dcterms.bibliographicCitation.volume
12
dcterms.bibliographicCitation.url
https://doi.org/10.1021/acs.jpclett.1c01447
refubium.affiliation
Physik
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.eissn
1948-7185
refubium.resourceType.provider
WoS-Alert