The surface of expanded face-centered tetragonal antiferromagnetic Mn films of a few atomic monolayers thickness grown epitaxially on Co/Cu(001) was investigated at room temperature by scanning tunneling microscopy and scanning tunneling spectroscopy using a ferromagnetic ring-shaped bulk iron probe. We show that the main contribution to the contrast modulation observed as a function of Mn thickness in differential conductance maps is not due to spin- polarized tunneling from a layerwise antiferromagnetic spin alignment. Instead, it is mainly of electronic origin resulting from layer-dependent electronic properties of the Mn film, probably related to different levels of intermixing with Co atoms.On the atomic scale, theMn surface demonstrates a geometrical reconstruction with a (12 × 2) periodicity in two orthogonal domains on the fourfold symmetric substrate with an apparent surface corrugation of up to 0.3 A° . Simultaneously recorded differential conductance maps show different textures in the two orthogonal domains, providing evidence for noncollinearity in the Mn surface spin structure.