Title:
Ligand discrimination of myoglobin in solution
Subtitle:
an iron L-edge X-ray absorption study of the active centre
Author(s):
Lange, Kathrin M.; Golnak, Ronny; Bonhommeau, Sébastien; Aziz, Emad F.
Year of publication:
2013
Available Date:
2015-02-09T10:36:16.980Z
Abstract:
Iron L-edge X-ray absorption spectra of the active centre of myoglobin in the
met-form, in the reduced form and upon ligation to O2, CO, NO and CN are
presented. The strength of ligation with the iron centre is finger-printed
through the variation of the L3 : L2 intensity ratio. Charge Transfer
Multiplet calculations are performed and give qualitative information about
oxidation states as well as charge transfer.
Part of Identifier:
ISSN (print): 1359-7345
DDC-Classification:
540 Chemie
Publication Type:
Wissenschaftlicher Artikel
Also published in:
Chemical Communications. - 49 (2013), 39, S. 4163-4165
URL of the Original Publication:
DOI of the Original Publication:
Department/institution:
Physik
Institut für Experimentalphysik