Haupttitel:
Ligand discrimination of myoglobin in solution
Titelzusatz:
an iron L-edge X-ray absorption study of the active centre
Autor*in:
Lange, Kathrin M.; Golnak, Ronny; Bonhommeau, Sébastien; Aziz, Emad F.
Datum der Freigabe:
2015-02-09T10:36:16.980Z
Abstract:
Iron L-edge X-ray absorption spectra of the active centre of myoglobin in the
met-form, in the reduced form and upon ligation to O2, CO, NO and CN are
presented. The strength of ligation with the iron centre is finger-printed
through the variation of the L3 : L2 intensity ratio. Charge Transfer
Multiplet calculations are performed and give qualitative information about
oxidation states as well as charge transfer.
Teil des Identifiers:
ISSN (print): 1359-7345
DDC-Klassifikation:
540 Chemie
Publikationstyp:
Wissenschaftlicher Artikel
Auch erschienen in:
Chemical Communications. - 49 (2013), 39, S. 4163-4165
Fachbereich/Einrichtung:
Physik
Institut für Experimentalphysik