Haupttitel:
A combined quantum-chemical and matrix-isolation study on molecular manganese
fluorides
Verfasser*in:
Brosi, Felix; Schlöder, Tobias; Schmidt, Alexei; Beckers, Helmut; Riedel, Sebastian
Datum der Freigabe:
2016-05-02T08:49:22.581Z
Abstract:
Molecular manganese fluorides were studied using quantum-chemical calculations
at DFT and CCSD(T) levels and experimentally by matrix-isolation techniques.
They were prepared by co-deposition of IR-laser ablated elemental manganese or
manganese trifluoride with F2 in an excess of Ne, Ar, or N2 or with neat F2 at
5–12 K. New IR bands in the Mn–F stretching region are detected and assigned
to matrix-isolated molecular MnFx (x = 1–3).
DDC-Klassifikation:
540 Chemie
Publikationstyp:
Wissenschaftlicher Artikel
Auch erschienen in:
Dalton Trans. - 45 (2016),12, S. 5038-5044
Fachbereich/Einrichtung:
Biologie, Chemie, Pharmazie