Title:
Photovoltaic properties of BiI3 with copper interstitials
Author(s):
Datta, Rupam; Herfert, Kai Trombotto; Többens, Daniel M.; Tischler, Pirmin; Peterlechner, Martin; Breitung, Ben; Habrik, Marcel; Bruder, Jan; Lemmer, Uli; Schorr, Susan; Colsmann, Alexander; Röhm, Holger
Year of publication:
2025
Available Date:
2025-10-21T05:14:30Z
Abstract:
The synthesis and photovoltaic effect of Cu3xBi1−xI3 (CBI) thin films were studied. Although CBI was originally inspired by the material class of Caswellsilverites (also known as Rudorffites), an XRD study showed that its crystal structure resembles a BiI3-cage with interstitial copper. CBI was found to demonstrate optoelectronic properties suitable for solar light harvesting, including a band gap of 1.66 eV and thermal stability up to 333 °C. The corresponding thin film solar cells achieved a peak power conversion efficiency of 0.65%.
Part of Identifier:
e-ISSN (online): 3033-4063
Keywords:
CBI
synthesis
photovoltaic effect
DDC-Classification:
540 Chemie und zugeordnete Wissenschaften
Publication Type:
Wissenschaftlicher Artikel
URL of the Original Publication:
DOI of the Original Publication:
Department/institution:
Geowissenschaften
Institut für Geologische Wissenschaften / Fachrichtung Geochemie, Hydrogeologie, Mineralogie