dc.contributor.author
Claude, Guilhem
dc.contributor.author
Ellwanger, Mathias A.
dc.contributor.author
Grippo, Adam
dc.contributor.author
Hernandez, Ritchie
dc.contributor.author
Figueroa, Joshua R.
dc.contributor.author
Abram, Ulrich
dc.date.accessioned
2025-05-06T08:31:29Z
dc.date.available
2025-05-06T08:31:29Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/47544
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-47262
dc.description.abstract
A stepwise ligand exchange starting from [Mn(CO)5Br] allows the synthesis of the heteroleptic isocyanide manganese(I) complex mer,trans-[Mn(CNp-FArDArF2)3(CNtBu)2Br] (DArF = 3,5-(CF3)2C6H3, tBu = tert-butyl). Subsequent reduction gave the first heteroleptic isocyanide manganese(−1) complex, [K(18-crown-6)][Mn(CNp-FArDArF2)3(CNtBu)2], exhibiting a five-coordinate, trigonal bipyramidal coordination sphere.
en
dc.format.extent
4 Seiten
dc.rights.uri
https://creativecommons.org/licenses/by/4.0/
dc.subject
isocyanide manganese(I) complex
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::540 Chemie und zugeordnete Wissenschaften
dc.title
A mixed isocyanide Mn(i) complex and its reduction to a metallate
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.doi
10.1039/D5DT00634A
dcterms.bibliographicCitation.journaltitle
Dalton Transactions
dcterms.bibliographicCitation.number
15
dcterms.bibliographicCitation.pagestart
6025
dcterms.bibliographicCitation.pageend
6028
dcterms.bibliographicCitation.volume
54
dcterms.bibliographicCitation.url
https://doi.org/10.1039/D5DT00634A
refubium.affiliation
Biologie, Chemie, Pharmazie
refubium.affiliation.other
Institut für Chemie und Biochemie
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.eissn
1477-9234
refubium.resourceType.provider
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