Title:
Unlocking New Frontiers: Photo-Isomerism and Magnetic Properties in Multifunctional Hetero-Tetra-Metallic Complexes
Author(s):
Suzana, Ingrid; Forté, Jérémy; Pillet, Sébastien; Bendeif, El-Eulmi; Malischewski, Moritz; Marvaud, Valérie
Year of publication:
2025
Available Date:
2025-04-10T07:59:05Z
Abstract:
Hetero-tetra-metallic complexes, FeNOCuLnCo (Ln=Gd, Tb, Dy), combining magnetic properties and photo-isomerism, were obtained through the rational assembly of the photo-switching nitroprusside anion FeNO with new magnetic Schiff base CuLnCo precursors. Herein, we describe the synthesis and characterisation of these compounds followed by a demonstration of their multifunctional character. Particularly noteworthy is the FeNOCuTbCo complex which is one of the few examples of a photo-isomerisable SMM.
Part of Identifier:
e-ISSN (online): 1521-3765
Keywords:
Hetero-poly-metallic
Multifunctionality
High-Spin molecules
Single-molecule magnet
Photo-isomerism
DDC-Classification:
540 Chemie und zugeordnete Wissenschaften
Publication Type:
Wissenschaftlicher Artikel
URL of the Original Publication:
DOI of the Original Publication:
Journaltitle:
Chemistry - A European Journal
Department/institution:
Biologie, Chemie, Pharmazie
Institut für Chemie und Biochemie
