dc.contributor.author
Junge, Florian
dc.contributor.author
Haag, Rainer
dc.date.accessioned
2025-02-14T05:46:13Z
dc.date.available
2025-02-14T05:46:13Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/46426
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-46139
dc.description.abstract
Catechol-derived polymers form stable coatings on a wide range of materials including challenging to coat low surface energy polymers. Whether modification of the coating polymer with fluorophilic or hydrophobic groups is a successful approach to further favor the coating of hydrophobic or fluorophilic surfaces with catechol-based polymers remains ambiguous. Herein, we report the effect of a series of catechol-derived polyglycerol (PG)-based coatings and monolayer coatings on the wettability of polytetrafluoroethylene (PTFE), polystyrene, and poly(methyl methacrylate) surfaces. Coatings with a longer hydrophilic PG block resulted in surface coatings with water contact angles (WCAs) around 60° independently of the modification and substrate, while coatings with a longer hydrophobic anchoring block possessed more diverse WCAs up to (129 ± 10)°. Despite the generally small impact of the fluorophilic modification for most substrate/coating combinations, some fluorophilic modified coatings reduce the WCA of PTFE below Berg’s limit of 65°, indicating a shielding of fluorous segments from the surface.
en
dc.format.extent
10 Seiten
dc.rights.uri
https://creativecommons.org/licenses/by/4.0/
dc.subject
Coating materials
en
dc.subject
Hydrocarbons
en
dc.subject
Hydrophobicity
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::540 Chemie und zugeordnete Wissenschaften
dc.title
Effect of Fluorophilic- and Hydrophobic-Modified Polyglycerol-Based Coatings on the Wettability of Low Surface Energy Polymers
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.doi
10.1021/acs.langmuir.4c04220
dcterms.bibliographicCitation.journaltitle
Langmuir
dcterms.bibliographicCitation.number
5
dcterms.bibliographicCitation.pagestart
3305
dcterms.bibliographicCitation.pageend
3314
dcterms.bibliographicCitation.volume
41
dcterms.bibliographicCitation.url
https://doi.org/10.1021/acs.langmuir.4c04220
refubium.affiliation
Biologie, Chemie, Pharmazie
refubium.affiliation.other
Institut für Chemie und Biochemie

refubium.funding
ACS Publications
refubium.note.author
Die Publikation wurde aus Open Access Publikationsgeldern der Freien Universität Berlin gefördert.
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.eissn
1520-5827