dc.contributor.author
Schlögl, Johanna
dc.contributor.author
Goldammer, Ole
dc.contributor.author
Bader, Julia
dc.contributor.author
Emmerling, Franziska
dc.contributor.author
Riedel, Sebastian
dc.date.accessioned
2024-06-05T07:51:14Z
dc.date.available
2024-06-05T07:51:14Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/43758
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-43473
dc.description.abstract
Common Lewis superacids often suffer from low thermal stability or complicated synthetic protocols, requiring multi-step procedures and expensive starting materials. This prevents their large-scale application. Herein, the easy and comparably cheap synthesis of high-purity aluminium tris(fluorosulfate) ([Al(SO3F)3]x, AFS) is presented. All starting materials are commercially available and no work-up is required. The superacidity of this thermally stable, polymeric Lewis acid is demonstrated using both theoretical and experimental methods. Furthermore, its synthetic and catalytic applicability, e.g. in bond heterolysis reactions and C–F bond activations, is shown.
en
dc.format.extent
7 Seiten
dc.rights.uri
https://creativecommons.org/licenses/by/4.0/
dc.subject
common Lewis superacids
en
dc.subject
low thermal stability
en
dc.subject
complicated synthetic protocols
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::540 Chemie und zugeordnete Wissenschaften
dc.title
Introducing AFS ([Al(SO3F)3]x) – a thermally stable, readily available, and catalytically active solid Lewis superacid
dc.type
Wissenschaftlicher Artikel
dc.date.updated
2024-06-03T07:03:53Z
dcterms.bibliographicCitation.doi
10.1039/d4sc01753f
dcterms.bibliographicCitation.journaltitle
Chemical Science
dcterms.bibliographicCitation.number
21
dcterms.bibliographicCitation.originalpublishername
The Royal Society of Chemistry
dcterms.bibliographicCitation.pagestart
8038
dcterms.bibliographicCitation.pageend
8044
dcterms.bibliographicCitation.volume
15
dcterms.bibliographicCitation.url
https://doi.org/10.1039/D4SC01753F
refubium.affiliation
Biologie, Chemie, Pharmazie
refubium.affiliation.other
Institut für Chemie und Biochemie
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.issn
2041-6520
dcterms.isPartOf.eissn
2041-6539
refubium.resourceType.provider
DeepGreen