dc.contributor.author
Senges, Gene
dc.contributor.author
Buzanich, Ana Guilherme
dc.contributor.author
Lindic, Tilen
dc.contributor.author
Gully, Tyler A.
dc.contributor.author
Winter, Marlon
dc.contributor.author
Radtke, Martin
dc.contributor.author
Röder, Bettina
dc.contributor.author
Steinhauer, Simon
dc.contributor.author
Paulus, Beate
dc.contributor.author
Riedel, Sebastian
dc.date.accessioned
2024-04-10T12:51:49Z
dc.date.available
2024-04-10T12:51:49Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/43132
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-42848
dc.description.abstract
The Simons process is an electrochemical fluorination method to prepare organofluorine compounds. Despite the wide application, the underlying mechanism is still unclear. We report the investigation of the black film formed on the surface of the anodes in aHF by an in situ Ni K-edge X-ray absorption near edge structure (XANES) investigation. An electrochemical cell for in situ X-ray absorption spectroscopy (XAS) is presented.
en
dc.format.extent
6 Seiten
dc.rights.uri
https://creativecommons.org/licenses/by/4.0/
dc.subject
Simons process
en
dc.subject
anodic black film
dc.subject
X-ray absorption spectroscopy
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::540 Chemie und zugeordnete Wissenschaften
dc.title
Unravelling highly oxidized nickel centers in the anodic black film formed during the Simons process by in situ X-ray absorption near edge structure spectroscopy
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.doi
10.1039/D3SC06081K
dcterms.bibliographicCitation.journaltitle
Chemical Science
dcterms.bibliographicCitation.number
12
dcterms.bibliographicCitation.pagestart
4504
dcterms.bibliographicCitation.pageend
4509
dcterms.bibliographicCitation.volume
15
dcterms.bibliographicCitation.url
https://doi.org/10.1039/D3SC06081K
refubium.affiliation
Biologie, Chemie, Pharmazie
refubium.affiliation.other
Institut für Chemie und Biochemie
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.eissn
2041-6539
refubium.resourceType.provider
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