dc.contributor.author
Toraman, Ahmet N.
dc.contributor.author
Fischer, Lukas
dc.contributor.author
Pérez-Bitrián, Alberto
dc.contributor.author
Wiesner, Anja
dc.contributor.author
Hoffmann, Kurt F.
dc.contributor.author
Riedel, Sebastian
dc.date.accessioned
2024-02-22T10:02:12Z
dc.date.available
2024-02-22T10:02:12Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/42323
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-42048
dc.description.abstract
Herein we report on the formation of the adduct salts [Xe(OTeF5)(pyF)][Al(OTeF5)4] (pyF = C5F5N, C5H3F2N) by abstraction of an –OTeF5 group from Xe(OTeF5)2 with the Lewis superacid Al(OTeF5)3 and subsequent adduct formation of the generated [XeOTeF5]+ cation with fluorinated pyridines. These salts represent the first xenonium cations with the weakly coordinating [Al(OTeF5)4]− anion. The strong oxidizing property of these compounds is further assessed.
en
dc.format.extent
4 Seiten
dc.rights.uri
https://creativecommons.org/licenses/by/4.0/
dc.subject
adduct salts
en
dc.subject
xenonium cations
en
dc.subject
strong oxidizing property
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::540 Chemie und zugeordnete Wissenschaften
dc.title
[Xe(OTeF5)(pyF)]+: a strong oxidizing xenonium(ii) teflate cation with N-donor bases
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.doi
10.1039/D3CC05560D
dcterms.bibliographicCitation.journaltitle
Chemical Communications
dcterms.bibliographicCitation.number
13
dcterms.bibliographicCitation.pagestart
1711
dcterms.bibliographicCitation.pageend
1714
dcterms.bibliographicCitation.volume
60
dcterms.bibliographicCitation.url
https://doi.org/10.1039/D3CC05560D
refubium.affiliation
Biologie, Chemie, Pharmazie
refubium.affiliation.other
Institut für Chemie und Biochemie
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.eissn
1364-548X
refubium.resourceType.provider
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