dc.contributor.author
Streit, Tim-Niclas
dc.contributor.author
Gomila, Rosa M.
dc.contributor.author
Sievers, Robin
dc.contributor.author
Frontera, Antonio
dc.contributor.author
Malischewski, Moritz
dc.date.accessioned
2024-02-06T09:00:24Z
dc.date.available
2024-02-06T09:00:24Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/42298
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-42023
dc.description.abstract
S–(CF3)Thianthrenium and S–(CF3)dibenzothiophenium cations form potent chalcogen bonds (ChBs) with [Mo(CO)5CN]−, yielding S2N2 supramolecular motifs. Crystal structures reveal shorter S⋯N contacts opposite the CF3 group compared to the aryl substituents. The energetic features of the ChBs have been studied using DFT calculations demonstrating the structure guiding role of ChBs.
en
dc.format.extent
5 Seiten
dc.rights.uri
https://creativecommons.org/licenses/by-nc/4.0/
dc.subject
sulfonium cations
en
dc.subject
chalcogen bond donors
en
dc.subject
cyanometalates
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::540 Chemie und zugeordnete Wissenschaften
dc.title
CF3-substituted sulfonium cations as efficient chalcogen bond donors towards cyanometalates
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.doi
10.1039/D3CE01155K
dcterms.bibliographicCitation.journaltitle
CrystEngComm
dcterms.bibliographicCitation.number
5
dcterms.bibliographicCitation.pagestart
594
dcterms.bibliographicCitation.pagestart
598
dcterms.bibliographicCitation.volume
26
dcterms.bibliographicCitation.url
https://doi.org/10.1039/D3CE01155K
refubium.affiliation
Biologie, Chemie, Pharmazie
refubium.affiliation.other
Institut für Chemie und Biochemie
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.eissn
1466-8033
refubium.resourceType.provider
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