dc.contributor.author
Haswell, Alex
dc.contributor.author
Tironi, Matteo
dc.contributor.author
Wang, Haoyue
dc.contributor.author
Hopkinson, Matthew N.
dc.date.accessioned
2024-02-02T09:08:48Z
dc.date.available
2024-02-02T09:08:48Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/42278
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-42004
dc.description.abstract
Deoxygenative perfluoroalkylthiolation reactions of readily available carboxylic acid derivatives have been developed using a series of 2-(perfluoroalkylthio)benzothiazolium (BT-SRF) reagents as convenient sources of perfluoroalkylthiolate anions. This method avoids pre-activation of the substrates and delivers rarely reported perfluoroalkyl thioesters featuring SRF groups up to C6F13. A survey of carboxylic acid substrates with the pentafluoroethylthiolating reagent BT-SC2F5 also revealed the generality of the approach as a method for accessing underexplored fluorinated compounds.
en
dc.format.extent
10 Seiten
dc.rights.uri
https://creativecommons.org/licenses/by/4.0/
dc.subject
Benzothiazolium reagents
en
dc.subject
Perfluoroalkyl groups
en
dc.subject
Deoxygenative reactions
en
dc.subject
Carboxylic acids
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::540 Chemie und zugeordnete Wissenschaften
dc.title
Deoxygenative perfluoroalkylthiolation of carboxylic acids with benzothiazolium reagents
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.articlenumber
110231
dcterms.bibliographicCitation.doi
10.1016/j.jfluchem.2023.110231
dcterms.bibliographicCitation.journaltitle
Journal of Fluorine Chemistry
dcterms.bibliographicCitation.volume
273
dcterms.bibliographicCitation.url
https://doi.org/10.1016/j.jfluchem.2023.110231
refubium.affiliation
Biologie, Chemie, Pharmazie
refubium.affiliation.other
Institut für Chemie und Biochemie
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.eissn
1873-3328
refubium.resourceType.provider
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