dc.contributor.author
Bui, Minh
dc.contributor.author
Hoffmann, Kurt F.
dc.contributor.author
Braun, Thomas
dc.contributor.author
Riedel, Sebastian
dc.contributor.author
Heinekamp, Christian
dc.contributor.author
Scheurell, Kerstin
dc.contributor.author
Scholz, Gudrun
dc.contributor.author
Stawski, Tomasz M.
dc.contributor.author
Emmerling, Franziska
dc.date.accessioned
2023-04-21T09:29:07Z
dc.date.available
2023-04-21T09:29:07Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/39050
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-38766
dc.description.abstract
An anion‐doped aluminium chlorofluoride AlCl0.1F2.8(OTeF5)0.1 (ACF‐teflate) was synthesized. The material contains pentafluoroorthotellurate (teflate) groups, which mimic fluoride ions electronically, but are sterically more demanding. They are embedded into the amorphous structure. The latter was studied by PDF analysis, EXAFS data and MAS NMR spectroscopy. The mesoporous powder is a Lewis superacid, and ATR‐IR spectra of adsorbed CD3CN reveal a blue‐shift of the adsorption band by 73 cm−1, which is larger than the shift for SbF5. Remarkably, ACF‐teflate catalyzes dehydrofluorination reactions of monofluoroalkanes to yield olefins in C6D6. In these cases, no Friedel‐Crafts products were formed.
en
dc.format.extent
6 Seiten
dc.rights
This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial‐NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
dc.rights.uri
https://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject
aluminium fluorides
en
dc.subject
aluminium teflates
en
dc.subject
C−F activation
en
dc.subject
Lewis superacids
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::540 Chemie und zugeordnete Wissenschaften
dc.title
An Amorphous Teflate Doped Aluminium Chlorofluoride: A Solid Lewis‐Superacid for the Dehydrofluorination of Fluoroalkanes
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.articlenumber
e202300350
dcterms.bibliographicCitation.doi
10.1002/cctc.202300350
dcterms.bibliographicCitation.journaltitle
ChemCatChem
dcterms.bibliographicCitation.number
7
dcterms.bibliographicCitation.volume
15
dcterms.bibliographicCitation.url
https://doi.org/10.1002/cctc.202300350
refubium.affiliation
Biologie, Chemie, Pharmazie
refubium.affiliation.other
Institut für Chemie und Biochemie
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.eissn
1867-3899
refubium.resourceType.provider
DeepGreen
