dc.contributor.author
Lin, Jinxiong
dc.contributor.author
Frost, Daniel S.
dc.contributor.author
Coles, Nathan T.
dc.contributor.author
Weber, Manuela
dc.contributor.author
Müller, Christian
dc.date.accessioned
2023-04-11T13:03:26Z
dc.date.available
2023-04-11T13:03:26Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/37399
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-37111
dc.description.abstract
A series of novel 3-N,N-dimethylaminofunctionalized phosphinines were synthesized and structurally characterized. DFT calculations showed that these aromatic phosphorus heterocycles possess stronger π-donor and σ-donor properties compared to the parent phosphinine C5H5P. With CuBr ⋅ SMe2, the corresponding complexes of the type [(phosphinine)2CuBr]2 are formed, which show the classical terminal σ-coordination mode of the phosphorus donor towards the Cu(I) center. Upon reaction with AuCl ⋅ SMe2, mononuclear phosphinine-Au(I)Cl complexes could be obtained and crystallographically characterized. Moreover, the presence of a SiMe3-group and a donor-functionality provide the possibility for post-synthetic ligand modifications. With CuCl ⋅ SMe2 the phosphinine-based hydrochloride salts forms a rare Cu(I) complex with a Cu4Cl4-core, that contains two pairs of differently coordinating phosphinine ligands.
en
dc.format.extent
7 Seiten
dc.rights.uri
https://creativecommons.org/licenses/by-nc/4.0/
dc.subject
Au(I) Complexes
en
dc.subject
Coordination Chemistry
en
dc.subject
Cu(I) Complexes
en
dc.subject
DFT Calculations
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::540 Chemie und zugeordnete Wissenschaften
dc.title
Copper(I) and Gold(I) Complexes of Aminofunctionalized Phosphinines: Synthesis and Structural Characterization
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.articlenumber
e202200365
dcterms.bibliographicCitation.doi
10.1002/zaac.202200365
dcterms.bibliographicCitation.journaltitle
Zeitschrift für anorganische und allgemeine Chemie
dcterms.bibliographicCitation.number
6-7
dcterms.bibliographicCitation.volume
649
dcterms.bibliographicCitation.url
https://doi.org/10.1002/zaac.202200365
refubium.affiliation
Biologie, Chemie, Pharmazie
refubium.affiliation.other
Institut für Chemie und Biochemie
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refubium.funding
DEAL Wiley
refubium.note.author
Die Publikation wurde aus Open Access Publikationsgeldern der Freien Universität Berlin gefördert.
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.eissn
1521-3749