dc.contributor.author
Duvinage, Daniel
dc.contributor.author
Janssen, Marvin
dc.contributor.author
Lork, Enno
dc.contributor.author
Grützmacher, Hansjörg
dc.contributor.author
Mebs, Stefan
dc.contributor.author
Beckmann, Jens
dc.date.accessioned
2022-11-10T09:18:26Z
dc.date.available
2022-11-10T09:18:26Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/35780
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-35495
dc.description.abstract
Kinetic stabilization using bulky m-terphenyl substituents is the key to the isolation of the diarylantimony and diarylbismuth phosphaethynolates (2,6-Mes2C6H3)2EPCO and the related N-heterocyclic carbene complexes (2,6-Mes2C6H3)2EP(O)C(IMe4) (E=Sb, Bi; IMe4=1,3,4,5-tetramethylimidazol-2-ylidene), which have been fully characterized crystallographically and spectroscopically. The experimental characterization was augmented by a DFT based real space bond indicator analysis of the electron density, including AIM, NCI, and ELI-D methods.
en
dc.format.extent
9 Seiten
dc.rights.uri
https://creativecommons.org/licenses/by/4.0/
dc.subject
Phosphaethynolate
en
dc.subject
N-heterocyclic carbene
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::540 Chemie und zugeordnete Wissenschaften
dc.title
Kinetic Stabilization of Heavier Bis(m-terphenyl)pnictogen Phosphaethynolates
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.articlenumber
e202200133
dcterms.bibliographicCitation.doi
10.1002/zaac.202200133
dcterms.bibliographicCitation.journaltitle
Zeitschrift für anorganische und allgemeine Chemie
dcterms.bibliographicCitation.number
19
dcterms.bibliographicCitation.volume
648
dcterms.bibliographicCitation.url
https://doi.org/10.1002/zaac.202200133
refubium.affiliation
Physik
refubium.affiliation.other
Institut für Experimentalphysik
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.eissn
1521-3749
refubium.resourceType.provider
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