dc.contributor.author
Dettling, Lea
dc.contributor.author
Papke, Martin
dc.contributor.author
Sklorz, Julian A. W.
dc.contributor.author
Buzsáki, Dániel
dc.contributor.author
Kelemen, Zsolt
dc.contributor.author
Weber, Manuela
dc.contributor.author
Nyulászi, László
dc.contributor.author
Müller, Christian
dc.date.accessioned
2022-08-08T05:24:14Z
dc.date.available
2022-08-08T05:24:14Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/35777
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-35492
dc.description.abstract
A novel bis-CF3-substituted diazaphosphole was synthesized selectively from hexafluoro-2-butyne and a 3H-1,2,3,4-triazaphosphole derivative. The [4+2] cycloaddition and subsequent cycloreversion reaction under elimination of pivaloyl nitrile affords the product in high yield. The heterocycle coordinates via the phosphorus atom to a W(CO)5-fragment and shows stronger π-accepting properties than the triazaphosphole.
en
dc.format.extent
4 Seiten
dc.rights.uri
https://creativecommons.org/licenses/by-nc/4.0/
dc.subject
diazaphospholes
en
dc.subject
cycloaddition
en
dc.subject
cycloreversion reaction
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::540 Chemie und zugeordnete Wissenschaften
dc.title
A new access to diazaphospholes via cycloaddition–cycloreversion reactions on triazaphospholes
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.doi
10.1039/D2CC02269A
dcterms.bibliographicCitation.journaltitle
Chemical Communications
dcterms.bibliographicCitation.number
56
dcterms.bibliographicCitation.pagestart
7745
dcterms.bibliographicCitation.pageend
7748
dcterms.bibliographicCitation.volume
58
dcterms.bibliographicCitation.url
https://doi.org/10.1039/D2CC02269A
refubium.affiliation
Biologie, Chemie, Pharmazie
refubium.affiliation.other
Institut für Chemie und Biochemie
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.eissn
1364-548X
refubium.resourceType.provider
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