dc.contributor.author
Greb, Lutz
dc.date.accessioned
2022-04-04T13:45:08Z
dc.date.available
2022-04-04T13:45:08Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/34573
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-34291
dc.description.abstract
Valence tautomerism has had a remarkable impact on several branches of transition metal chemistry. By switching between different valence tautomeric states, physicochemical properties and reactivities can be triggered reversibly. Is this phenomenon transferrable into the p-block – or is it already happening there? This Perspective collects observations of p-block element-ligand systems that might be assignable to valence tautomerism. Further, it discusses occurrences in p-block element compounds that exhibit the related effect of redox-induced electron transfer. As disclosed, the concept of valence tautomerism with p-block elements is at a very early stage. However, given the substantial disparity in the properties of those elements in different redox states, it might offer a valid extension for future developments in main group catalysis.
en
dc.format.extent
7 Seiten
dc.rights.uri
https://creativecommons.org/licenses/by-nc/4.0/
dc.subject
Electromerism
en
dc.subject
Main group elements
en
dc.subject
p-Block elements
en
dc.subject
Redox chemistry
en
dc.subject
Valence tautomerism
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::546 Anorganische Chemie
dc.title
Valence Tautomerism of p-Block Element Compounds – An Eligible Phenomenon for Main Group Catalysis?
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.articlenumber
e202100871
dcterms.bibliographicCitation.doi
10.1002/ejic.202100871
dcterms.bibliographicCitation.journaltitle
European Journal of Inorganic Chemistry
dcterms.bibliographicCitation.number
3
dcterms.bibliographicCitation.volume
2022
dcterms.bibliographicCitation.url
https://doi.org/10.1002/ejic.202100871
refubium.affiliation
Biologie, Chemie, Pharmazie
refubium.affiliation.other
Institut für Chemie und Biochemie
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.eissn
1099-0682
refubium.resourceType.provider
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