dc.contributor.author
Pröhm, Patrick
dc.contributor.author
Schwarze, Nico
dc.contributor.author
Müller, Carsten
dc.contributor.author
Steinhauer, Simon
dc.contributor.author
Beckers, Helmut
dc.contributor.author
Rupf, Susanne M.
dc.contributor.author
Riedel, Sebastian
dc.date.accessioned
2021-06-21T13:07:52Z
dc.date.available
2021-06-21T13:07:52Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/31098
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-30834
dc.description.abstract
We present the synthesis and characterization of the first non-classical Cl(I) polyinterhalide [NMe4][F(ClF)3] as well as the homologous polychloride [NPr3Me][Cl7]. Both salts were obtained from the reaction of the corresponding ammonium chlorides with ClF or Cl2, respectively. Quantum-chemical investigations predict an unexpected planar structure for the [F(ClF)3]− anion.
en
dc.format.extent
4 Seiten
dc.rights.uri
https://creativecommons.org/licenses/by/4.0/
dc.subject
non-classical Cl(I) polyinterhalide
en
dc.subject
homologous polychloride
en
dc.subject
characterization
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::540 Chemie und zugeordnete Wissenschaften
dc.title
Non-classical polyinterhalides of chlorine monofluoride: experimental and theoretical characterization of [F(ClF)3]−
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.doi
10.1039/D1CC01088C
dcterms.bibliographicCitation.journaltitle
Chemical Communications
dcterms.bibliographicCitation.number
39
dcterms.bibliographicCitation.pagestart
4843
dcterms.bibliographicCitation.pageend
4846
dcterms.bibliographicCitation.volume
57
dcterms.bibliographicCitation.url
https://doi.org/10.1039/D1CC01088C
refubium.affiliation
Biologie, Chemie, Pharmazie
refubium.affiliation.other
Institut für Chemie und Biochemie
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.eissn
1364-548X
refubium.resourceType.provider
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