dc.contributor.author
Schmid, Jonas R.
dc.contributor.author
Pröhm, Patrick
dc.contributor.author
Voßnacker, Patrick
dc.contributor.author
Thiele, Günter
dc.contributor.author
Ellwanger, Mathias
dc.contributor.author
Steinhauer, Simon
dc.contributor.author
Riedel, Sebastian
dc.date.accessioned
2021-01-11T11:55:09Z
dc.date.available
2021-01-11T11:55:09Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/29213
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-28961
dc.description.abstract
We present a facile synthesis of the soluble fluoridobromates [NEt3Me][BrF4] and [NEt3Me][Br2F7] via fluorination of the corresponding bromide salts in acetonitrile, propionitrile or bromine. We structurally characterized the [BrF2]– anion, an intermediate during the synthesis, for the first time. Additionally, the dissolution of noble metals to form the corresponding halometallates as well as the application of [NEt3Me][BrF4] as a fluorination agent for disulfides to form pentafluorosulfanyls was studied.
en
dc.rights.uri
https://creativecommons.org/licenses/by/4.0/
dc.subject
Fluoridobromates
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::570 Biowissenschaften; Biologie::572 Biochemie
dc.title
Soluble Fluoridobromates as Well‐Behaved Strong Fluorination Reagents
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.doi
10.1002/ejic.202000847
dcterms.bibliographicCitation.journaltitle
European Journal of Inorganic Chemistry
dcterms.bibliographicCitation.number
47
dcterms.bibliographicCitation.pagestart
4497
dcterms.bibliographicCitation.pageend
4500
dcterms.bibliographicCitation.volume
2020
dcterms.bibliographicCitation.url
https://doi.org/10.1002/ejic.202000847
refubium.affiliation
Biologie, Chemie, Pharmazie
refubium.affiliation.other
Institut für Chemie und Biochemie
refubium.funding
DEAL Wiley
refubium.note.author
Die Publikation wurde aus Open Access Publikationsgeldern der Freien Universität Berlin gefördert.
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.eissn
1099-0682
