dc.contributor.author
Schmid, Jonas R.
dc.contributor.author
Pröhm, Patrick
dc.contributor.author
Voßnacker, Patrick
dc.contributor.author
Thiele, Günter
dc.contributor.author
Ellwanger, Mathias
dc.contributor.author
Steinhauer, Simon
dc.contributor.author
Riedel, Sebastian
dc.date.accessioned
2021-01-11T11:55:09Z
dc.date.available
2021-01-11T11:55:09Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/29213
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-28961
dc.description.abstract
We present a facile synthesis of the soluble fluoridobromates [NEt3Me][BrF4] and [NEt3Me][Br2F7] via fluorination of the corresponding bromide salts in acetonitrile, propionitrile or bromine. We structurally characterized the [BrF2]– anion, an intermediate during the synthesis, for the first time. Additionally, the dissolution of noble metals to form the corresponding halometallates as well as the application of [NEt3Me][BrF4] as a fluorination agent for disulfides to form pentafluorosulfanyls was studied.
en
dc.rights.uri
https://creativecommons.org/licenses/by/4.0/
dc.subject
Fluoridobromates
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::570 Biowissenschaften; Biologie::572 Biochemie
dc.title
Soluble Fluoridobromates as Well‐Behaved Strong Fluorination Reagents
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.doi
10.1002/ejic.202000847
dcterms.bibliographicCitation.journaltitle
European Journal of Inorganic Chemistry
dcterms.bibliographicCitation.number
47
dcterms.bibliographicCitation.pagestart
4497
dcterms.bibliographicCitation.pageend
4500
dcterms.bibliographicCitation.volume
2020
dcterms.bibliographicCitation.url
https://doi.org/10.1002/ejic.202000847
refubium.affiliation
Biologie, Chemie, Pharmazie
refubium.affiliation.other
Institut für Chemie und Biochemie
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refubium.funding
DEAL Wiley
refubium.note.author
Die Publikation wurde aus Open Access Publikationsgeldern der Freien Universität Berlin gefördert.
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.eissn
1099-0682