dc.contributor.author
Hämmerling, Sebastian
dc.contributor.author
Vossnacker, Patrick
dc.contributor.author
Steinhauer, Simon
dc.contributor.author
Beckers, Helmut
dc.contributor.author
Riedel, Sebastian
dc.date.accessioned
2020-11-16T13:06:10Z
dc.date.available
2020-11-16T13:06:10Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/28879
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-28628
dc.description.abstract
The dimethylchloronium salt [Me2Cl][Al(OTeF5)(4)] is used to methylate electron-deficient aromatic systems in Friedel-Crafts type reactions as shown by the synthesis ofN-methylated cations, such as [MeNC5F5](+), [MeNC5F4I](+), and [MeN3C3F3](+). To gain a better understanding of such fundamental Friedel-Crafts reactions, the role of the dimethylchloronium cation has been evaluated by quantum-chemical calculations.
en
dc.format.extent
8 Seiten
dc.rights.uri
https://creativecommons.org/licenses/by/4.0/
dc.subject
electrophilic substitution
en
dc.subject
halonium ions
en
dc.subject
reaction mechanism
en
dc.subject
weakly coordinating anion
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie::540 Chemie und zugeordnete Wissenschaften
dc.title
Friedel-Crafts Type Methylation with Dimethylhalonium Salts
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.doi
10.1002/chem.202001457
dcterms.bibliographicCitation.journaltitle
Chemistry - A European Journal
dcterms.bibliographicCitation.number
63
dcterms.bibliographicCitation.pagestart
14377
dcterms.bibliographicCitation.pageend
14384
dcterms.bibliographicCitation.volume
26
dcterms.bibliographicCitation.url
https://doi.org/10.1002/chem.202001457
refubium.affiliation
Biologie, Chemie, Pharmazie
refubium.affiliation.other
Institut für Chemie und Biochemie
refubium.funding
DEAL Wiley
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.eissn
1521-3765
refubium.resourceType.provider
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