dc.contributor.author
Nehrkorn, Joscha
dc.contributor.author
Holldack, Karsten
dc.contributor.author
Bittl, Robert
dc.contributor.author
Schnegg, Alexander
dc.date.accessioned
2020-04-09T10:39:47Z
dc.date.available
2020-04-09T10:39:47Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/27092
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-26853
dc.description.abstract
We describe frequency-domain Fourier-transform THz-EPR as a method to assign spin-coupling parameters of high-spin (S > 1/2) systems with very large zero-field splittings. The instrumental foundations of synchrotron-based FD-FT THz-EPR are presented, alongside with a discussion of frequency-domain EPR simulation routines. The capabilities of this approach is demonstrated for selected mono- and multinuclear HS systems. Finally, we discuss remaining challenges and give an outlook on the future prospects of the technique.
en
dc.format.extent
31 Seiten
dc.rights.uri
https://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subject
frequency-domain EPR spectroscopy
en
dc.subject
zero-field splitting
en
dc.subject
high-spin transition-metal ion
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::530 Physik::530 Physik
dc.title
Recent progress in synchrotron-based frequency-domain Fourier-transform THz-EPR
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.doi
10.1016/j.jmr.2017.04.001
dcterms.bibliographicCitation.journaltitle
Journal of magnetic resonance
dcterms.bibliographicCitation.pagestart
10
dcterms.bibliographicCitation.pageend
19
dcterms.bibliographicCitation.volume
280
dcterms.bibliographicCitation.url
https://doi.org/10.1016/j.jmr.2017.04.001
refubium.affiliation
Physik
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.issn
0022-2364
dcterms.isPartOf.eissn
1557-8968
