dc.contributor.author
Nasibulov, Egor A.
dc.contributor.author
Behrends, Jan
dc.contributor.author
Kulik, Leonid V.
dc.contributor.author
Ivanov, Konstantin L.
dc.date.accessioned
2019-08-28T12:01:42Z
dc.date.available
2019-08-28T12:01:42Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/25375
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-4080
dc.description.abstract
A theoretical description of pulsed reaction yield detected magnetic resonance (RYDMR) is proposed. In RYDMR, magnetic resonance spectra of radical pairs (RPs) are indirectly detected by monitoring their recombination yield. Such a detection method is significantly more sensitive than conventional electron paramagnetic resonance (EPR), but design of appropriate pulse sequences for RYDMR requires additional effort because of a different observable. In this work various schemes for generating spin-echo like signals and detecting them by RYDMR are treated. Specifically, we consider refocusing of zero-quantum coherences (ZQCs) and single-quantum coherences (SQCs) by selective as well as by non-selective pulses and formulate a general analytical approach to pulsed RYDMR, which makes an efficient use of the product operator formalism. We anticipate that these results are of importance for RYDMR studies of elusive paramagnetic particles, notably, in organic semiconductors.
en
dc.rights.uri
http://www.fu-berlin.de/sites/refubium/rechtliches/Nutzungsbedingungen
dc.subject
organic semiconductors
en
dc.subject
spin chemistry
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::530 Physik::530 Physik
dc.title
Theoretical Description of Pulsed RYDMR: Refocusing Zero-Quantum and Single Quantum Coherences
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation.doi
10.1515/zpch-2016-0817
dcterms.bibliographicCitation.journaltitle
Zeitschrift für physikalische Chemie
dcterms.bibliographicCitation.number
2
dcterms.bibliographicCitation.volume
231
dcterms.bibliographicCitation.url
https://doi.org/10.1515/zpch-2016-0817
refubium.affiliation
Physik
refubium.resourceType.isindependentpub
no
dcterms.accessRights.openaire
open access
dcterms.isPartOf.issn
0942-9352
dcterms.isPartOf.eissn
2196-7156