dc.contributor.author
Matamoros-Veloza, Adriana
dc.contributor.author
Cespedes, Oscar
dc.contributor.author
Johnson, Benjamin R. G.
dc.contributor.author
Stawski, Tomasz M.
dc.contributor.author
Terranova, Umberto
dc.contributor.author
Leeuw, Nora H.
dc.contributor.author
Benning, Liane G.
dc.date.accessioned
2018-09-05T07:25:18Z
dc.date.available
2018-09-05T07:25:18Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/22801
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-599
dc.description.abstract
Iron sulfur (Fe–S) phases have been implicated in the emergence of life on early Earth due to their catalytic role in the synthesis of prebiotic molecules. Similarly, Fe–S phases are currently of high interest in the development of green catalysts and energy storage. Here we report the synthesis and structure of a nanoparticulate phase (FeSnano) that is a necessary solid-phase precursor to the conventionally assumed initial precipitate in the iron sulfide system, mackinawite. The structure of FeSnano contains tetrahedral iron, which is compensated by monosulfide and polysulfide sulfur species. These together dramatically affect the stability and enhance the reactivity of FeSnano.
en
dc.format.extent
7 Seiten
de
dc.rights.uri
https://creativecommons.org/licenses/by/4.0/
de
dc.subject
Element cycles
en
dc.subject
Nanoparticles
en
dc.subject
Synthesis and processing
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::550 Geowissenschaften, Geologie::551 Geologie, Hydrologie, Meteorologie
de
dc.title
A highly reactive precursor in the iron sulfide system
de
dc.type
Wissenschaftlicher Artikel
de
dcterms.bibliographicCitation.articlenumber
3125
dcterms.bibliographicCitation.journaltitle
Nature Communications
dcterms.bibliographicCitation.volume
9
dcterms.bibliographicCitation.url
https://doi.org/10.1038/s41467-018-05493-x
de
refubium.affiliation
Geowissenschaften
de
refubium.affiliation.other
Institut für Geologische Wissenschaften / Fachrichtung Geochemie, Hydrogeologie, Mineralogie
de
refubium.note.author
Der Artikel wurde in einer reinen Open-Access-Zeitschrift publiziert.
de
refubium.resourceType.isindependentpub
no
de
dcterms.accessRights.openaire
open access
dcterms.isPartOf.issn
2041-1723
