dc.contributor.author
Roy, Souvik
dc.contributor.author
Bhunia, Asamanjoy
dc.contributor.author
Schuth, Nils
dc.contributor.author
Haumann, Michael
dc.contributor.author
Ott, Sascha
dc.date.accessioned
2018-08-06T14:01:08Z
dc.date.available
2018-08-06T14:01:08Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/22652
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-453
dc.description.abstract
A cobaloxime H2 evolution catalyst with a hydroxo-functionalized pyridine ligand, Co(dmgH)2(4-HEP)Cl [dmgH = dimethylglyoxime, 4-HEP = 4-(2-hydroxyethyl)pyridine] was immobilized on a chromium terephthalate metal–organic framework (MOF), MIL-101(Cr), to construct a MOF-catalyst hybrid which displays good photocatalytic H2 evolution activity. The longevity of the cobaloxime catalyst is increased by MOF incorporation, but limited by the stability of the cobalt–pyridine bond under turnover conditions.
en
dc.format.extent
5 Seiten
de
dc.rights.uri
https://creativecommons.org/licenses/by-nc/3.0/
de
dc.subject
cobaloxime catalyst
en
dc.subject.ddc
500 Naturwissenschaften und Mathematik::570 Biowissenschaften; Biologie::571 Physiologie und verwandte Themen
de
dc.title
Light-driven hydrogen evolution catalyzed by a cobaloxime catalyst incorporated in a MIL-101(Cr) metal–organic framework
de
dc.type
Wissenschaftlicher Artikel
de
dcterms.bibliographicCitation.doi
10.1039/c8se00072g
dcterms.bibliographicCitation.journaltitle
Sustainable Energy & Fuels
dcterms.bibliographicCitation.pagestart
1148
dcterms.bibliographicCitation.pageend
1152
dcterms.bibliographicCitation.volume
2
dcterms.bibliographicCitation.url
https://doi.org/10.1039/c8se00072g
de
refubium.affiliation
Physik
de
refubium.resourceType.isindependentpub
no
de
dcterms.accessRights.openaire
open access
dcterms.isPartOf.issn
2398-4902
