dc.contributor.author
Feifel, R.
dc.contributor.author
Eland, J. H. D.
dc.contributor.author
Carniato, S.
dc.contributor.author
Selles, P.
dc.contributor.author
Puettner, R.
dc.contributor.author
Koulentianos, D.
dc.contributor.author
Marchenko, T.
dc.contributor.author
Journel, L.
dc.contributor.author
Guillemin, R. [u.a.]
dc.date.accessioned
2018-06-08T11:11:41Z
dc.date.available
2017-11-13T09:43:11.219Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/21788
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-25076
dc.description.abstract
Recent advances in X-ray instrumentation have made it possible to measure the
spectra of an essentially unexplored class of electronic states associated
with double inner-shell vacancies. Using the technique of single electron
spectroscopy, spectra of states in CS2 and SF6 with a double hole in the
K-shell and one electron exited to a normally unoccupied orbital have been
obtained. The spectra are interpreted with the aid of a high-level theoretical
model giving excellent agreement with the experiment. The results shed new
light on the important distinction between direct and conjugate shake-up in a
molecular context. In particular, systematic similarities and differences
between pre-edge states near single core holes investigated in X-ray
absorption spectra and the corresponding states near double core holes studied
here are brought out.
en
dc.rights.uri
http://creativecommons.org/licenses/by/4.0/
dc.subject
Atomic and molecular interactions with photons
dc.subject
Electronic structure of atoms and molecules
dc.subject.ddc
500 Naturwissenschaften und Mathematik::530 Physik
dc.title
Cationic double K-hole pre-edge states of CS2 and SF6
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation
Scientific Reports. - 7 (2017), Artikel Nr. 13317
dcterms.bibliographicCitation.doi
10.1038/s41598-017-13607-6
dcterms.bibliographicCitation.url
http://www.nature.com/articles/s41598-017-13607-6
refubium.affiliation
Physik
de
refubium.mycore.fudocsId
FUDOCS_document_000000028470
refubium.note.author
Der Artikel wurde in einer reinen Open-Access-Zeitschrift publiziert.
refubium.resourceType.isindependentpub
no
refubium.mycore.derivateId
FUDOCS_derivate_000000009100
dcterms.accessRights.openaire
open access