dc.contributor.author
Nachtigall, Olaf
dc.contributor.author
Hagenbach, Adelheid
dc.contributor.author
Wiecko, Jelena
dc.contributor.author
Lentz, Dieter
dc.contributor.author
Abram, Ulrich
dc.contributor.author
Spandl, Johann
dc.date.accessioned
2018-06-08T10:36:11Z
dc.date.available
2017-01-12T08:23:22.892Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/20727
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-24026
dc.description.abstract
We report a study on the structure directing effects of functional groups and
counterions. The aim was to find a facile and high yielding synthetic
procedure to obtain polyoxometalate (POM) building blocks for post-
functionalisation. Therefore, solvothermal reactions of VOSO4 with various
tris(hydroxymethyl)methane derivatives in alkaline methanolic solutions were
investigated. In doing so, new POM fragments were isolated and characterised.
The binding modes of the functionalised tripodal alkoxides turned out to be
surprisingly different.
en
dc.rights.uri
http://creativecommons.org/licenses/by-nc/3.0/
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie
dc.title
Functional polyoxometalates from solvothermal reactions of VOSO4 with tripodal
alkoxides – a study on the reactivity of different “tris” derivatives
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation
Dalton Trans.- 46 (2017),S. 509-516
dcterms.bibliographicCitation.doi
10.1039/C6DT03638D
dcterms.bibliographicCitation.url
http://pubs.rsc.org/en/Content/ArticleLanding/2017/DT/C6DT03638D#!divAbstract
refubium.affiliation
Biologie, Chemie, Pharmazie
de
refubium.funding
OpenAccess Publikation in Allianzlizenz
refubium.funding.id
Au-028834
refubium.mycore.fudocsId
FUDOCS_document_000000026122
refubium.resourceType.isindependentpub
no
refubium.mycore.derivateId
FUDOCS_derivate_000000007510
dcterms.accessRights.openaire
open access
