dc.contributor.author
Weisser, Fritz
dc.contributor.author
Klein, Johannes E. M. N.
dc.contributor.author
Sarkar, Biprajit
dc.contributor.author
Plietker, Bernd
dc.date.accessioned
2018-06-08T04:13:30Z
dc.date.available
2015-03-02T14:13:56.015Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/16845
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-21026
dc.description.abstract
Bu4N[Fe(CO)3(NO)] displays unique catalytic properties in electron-transfer
catalysis such as in allylic substitutions, hydrosilylation,
transesterifications, or carbene transfer chemistry. Herein we present a
detailed spectroelectrochemical investigation of this complex that unravels an
interesting electrochemical–chemical transformation in which two parts of
[Fe(CO)3(NO)]− are oxidized and undergo a disproportionation in the presence
of CO to [Fe(CO)5] and [Fe(CO)2(NO)2]. Upon re-reduction the former two
complexes regenerate [Fe(CO)3(NO)]− to about 85%
en
dc.rights.uri
http://www.rsc.org/AboutUs/Copyright/LicencetoPublishforjournals.asp
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie
dc.title
Spectroelectrochemical investigation of Bu4N[Fe(CO)3(NO)]
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation
Dalton Trans. - 43 (2014),2 , S. 883-887
dc.title.subtitle
identification of a reversible EC-mechanism
dcterms.bibliographicCitation.doi
10.1039/C3DT51998H
dcterms.bibliographicCitation.url
http://pubs.rsc.org/en/Content/ArticleLanding/2014/DT/C3DT51998H#!divAbstract
refubium.affiliation
Biologie, Chemie, Pharmazie
de
refubium.mycore.fudocsId
FUDOCS_document_000000021942
refubium.resourceType.isindependentpub
no
refubium.mycore.derivateId
FUDOCS_derivate_000000004599
dcterms.accessRights.openaire
open access
