dc.contributor.author
Cera, Luca
dc.contributor.author
Schalley, Christoph A.
dc.date.accessioned
2018-06-08T03:59:55Z
dc.date.available
2016-09-26T10:30:32.890Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/16377
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-20560
dc.description.abstract
The high vacuum inside a mass spectrometer offers unique conditions to broaden
our view on the reactivity of supramolecules. Because dynamic exchange
processes between complexes are efficiently suppressed, the intrinsic and
intramolecular reactivity of the complexes of interest is observed. Besides
this, the significantly higher strength of non-covalent interactions in the
absence of competing solvent allows processes to occur that are unable to
compete in solution. The present review highlights a series of examples
illustrating different aspects of supramolecular gas-phase reactivity ranging
from the dissociation and formation of covalent bonds in non-covalent
complexes through the reactivity in the restricted inner phase of container
molecules and step-by-step mechanistic studies of organocatalytic reaction
cycles to cage contraction reactions, processes induced by electron capture,
and finally dynamic molecular motion within non-covalent complexes as
unravelled by hydrogen–deuterium exchange processes performed in the gas
phase.
en
dc.rights.uri
http://www.rsc.org/journals-books-databases/open-access/green-open-access/
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie
dc.title
Supramolecular reactivity in the gas phase: investigating the intrinsic
properties of non-covalent complexes
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation
Chemical Society Reviews. - 43 (2014), 6, S. 1800-1812
dcterms.bibliographicCitation.doi
10.1039/C3CS60360A
dcterms.bibliographicCitation.url
http://pubs.rsc.org/en/content/articlelanding/2014/cs/c3cs60360a#!divAbstract
refubium.affiliation
Biologie, Chemie, Pharmazie
de
refubium.mycore.fudocsId
FUDOCS_document_000000025415
refubium.resourceType.isindependentpub
no
refubium.mycore.derivateId
FUDOCS_derivate_000000007105
dcterms.accessRights.openaire
open access