dc.contributor.author
Golnak, Ronny
dc.contributor.author
Bokarev, Sergey I.
dc.contributor.author
Seidel, Robert
dc.contributor.author
Xiao, Jie
dc.contributor.author
Grell, Gilbert
dc.contributor.author
Atak, Kaan
dc.contributor.author
Unger, Isaak
dc.contributor.author
Thürmer, Stephan
dc.contributor.author
Aziz, Saadullah G.
dc.contributor.author
Kühn, Oliver
dc.contributor.author
Winter, Bernd
dc.contributor.author
Aziz, Emad F.
dc.date.accessioned
2018-06-08T03:56:32Z
dc.date.available
2016-06-16T11:18:38.997Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/16268
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-20452
dc.description.abstract
L-edge soft X-ray spectroscopy has been proven to be a powerful tool to
unravel the peculiarities of electronic structure of transition metal
compounds in solution. However, the X-ray absorption spectrum is often probed
in the total or partial fluorescence yield modes, what leads to inherent
distortions with respect to the true transmission spectrum. In the present
work, we combine photon- and electron-yield experimental techniques with
multi-reference first principles calculations. Exemplified for the
prototypical FeCl2 aqueous solution we demonstrate that the partial yield
arising from the Fe3s → 2p relaxation is a more reliable probe of the
absorption spectrum than the Fe3d → 2p one. For the bonding-relevant 3d → 2p
channel we further provide the basis for the joint analysis of resonant
photoelectron and inelastic X-ray scattering spectra. Establishing the common
energy reference allows to assign both spectra using the complementary
information provided through electron-out and photon-out events.
en
dc.rights.uri
http://creativecommons.org/licenses/by/4.0/
dc.subject.ddc
500 Naturwissenschaften und Mathematik
dc.title
Joint Analysis of Radiative and Non-Radiative Electronic Relaxation Upon X-ray
Irradiation of Transition Metal Aqueous Solutions
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation
Scientific Reports. - 6 (2016), Artikel Nr. 24659
dcterms.bibliographicCitation.doi
10.1038/srep24659
dcterms.bibliographicCitation.url
http://www.nature.com/articles/srep24659
refubium.affiliation
Biologie, Chemie, Pharmazie
de
refubium.affiliation
Physik
de
refubium.mycore.fudocsId
FUDOCS_document_000000024841
refubium.note.author
Der Artikel wurde in einer Open-Access-Zeitschrift publiziert.
refubium.resourceType.isindependentpub
no
refubium.mycore.derivateId
FUDOCS_derivate_000000006642
dcterms.accessRights.openaire
open access