dc.contributor.author
Bertorelle, Franck
dc.contributor.author
Hamouda, Ramzi
dc.contributor.author
Rayane, Driss
dc.contributor.author
Broyer, Michel
dc.contributor.author
Antoine, Rodolphe
dc.contributor.author
Dugourd, Philippe
dc.contributor.author
Gell, Lars
dc.contributor.author
Kulesza, Alexander
dc.contributor.author
Mitric, Roland
dc.contributor.author
Bonačić-Koutecký, Vlasta
dc.date.accessioned
2018-06-08T03:53:50Z
dc.date.available
2015-01-05T10:03:12.672Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/16168
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-20352
dc.description.abstract
We report a simple synthesis of silver:glutathione (Ag:SG) clusters using a
cyclic reduction under oxidative conditions. Two syntheses are described which
lead to solutions containing well-defined Ag31(SG)19 and Ag15(SG)11 clusters
that have been characterized by mass spectrometry. The optical properties of
silver:glutathione (Ag:SG) cluster solutions have been investigated
experimentally. In particular, the solution containing Ag15(SG)11 clusters
shows a bright and photostable emission. For Ag31(SG)19 and Ag15(SG)11
clusters, the comparison of experimental findings with DFT and TDDFT
calculations allowed us to reveal the structural and electronic properties of
such low nuclearity liganded silver clusters.
en
dc.rights.uri
http://www.rsc.org/AboutUs/Copyright/LicencetoPublishforjournals.asp
dc.subject.ddc
500 Naturwissenschaften und Mathematik::530 Physik
dc.title
Synthesis, characterization and optical properties of low nuclearity liganded
silver clusters
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation
Nanoscale. - 5 (2013), 12, S. 5637-5643
dc.identifier.sepid
32746
dc.title.subtitle
Ag31(SG)19 and Ag15(SG)11
dcterms.bibliographicCitation.doi
10.1039/C3NR00677H
dcterms.bibliographicCitation.url
http://dx.doi.org/10.1039/c3nr00677h
refubium.affiliation
Physik
de
refubium.affiliation.other
Institut für Theoretische Physik
refubium.mycore.fudocsId
FUDOCS_document_000000021502
refubium.resourceType.isindependentpub
no
refubium.mycore.derivateId
FUDOCS_derivate_000000004313
dcterms.accessRights.openaire
open access
dcterms.isPartOf.issn
2040-3364
