dc.contributor.author
Boymans, Evert H.
dc.contributor.author
Janssen, M. C. C.
dc.contributor.author
Müller, Christian
dc.contributor.author
Lutz, Martin
dc.contributor.author
Vogt, Dieter
dc.date.accessioned
2018-06-08T03:47:17Z
dc.date.available
2015-03-10T10:39:41.997Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/15926
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-20113
dc.description.abstract
Usually the Rh-catalyzed hydroformylation of styrene predominantly yields the
branched, chiral aldehyde. An inversion of regioselectivity can be achieved
using strong π-acceptor ligands. Binaphthol-based diphosphite and bis
(dipyrrolyl-phosphorodiamidite) ligands were applied in the Rh-catalyzed
hydroformylation of styrene. High selectivities up to 83% of 3-phenylpropanal
were obtained with 1,1-bi-2-naphthol-based bis(dipyrrolyl-phosphorodiamidite)
with virtually no hydrogenation to ethyl benzene. The coordination chemistry
of those ligands towards Rh(I) was investigated spectroscopically and
structurally.
en
dc.rights.uri
http://www.rsc.org/help-legal/legal/copyright-permissions
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie
dc.title
Rh-catalyzed linear hydroformylation of styrene
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation
Dalton Transactions. - 42 (2013), 1, S.137-142
dc.identifier.sepid
26016
dcterms.bibliographicCitation.doi
10.1039/C2DT31738A
dcterms.bibliographicCitation.url
http://dx.doi.org/10.1039/c2dt31738a
refubium.affiliation
Biologie, Chemie, Pharmazie
de
refubium.mycore.fudocsId
FUDOCS_document_000000022004
refubium.resourceType.isindependentpub
no
refubium.mycore.derivateId
FUDOCS_derivate_000000004645
dcterms.accessRights.openaire
open access
dcterms.isPartOf.issn
1477-9226
