dc.contributor.author
Zimmer, Reinhold
dc.contributor.author
Reissig, Hans-Ulrich
dc.date.accessioned
2018-06-08T03:43:03Z
dc.date.available
2014-10-20T12:43:54.223Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/15785
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-19972
dc.description.abstract
Alkoxyallenes are unusually versatile C3 building blocks in organic synthesis.
Hence this tutorial review summarizes the most important transformations,
including subsequent reactions and their applications in the synthesis of
relevant compounds, e.g. natural products. The reactivity patterns involved
and the synthons derived from alkoxyallenes are presented. Often alkoxyallenes
can serve as substitutes of acrolein or acrolein acetals, utilisation of which
has already led to interesting products. Most important is the use of
lithiated alkoxyallenes which smoothly react with a variety of electrophiles
and lead to products with unique substitution patterns. The heterocycles or
carbocycles formed are intermediates for the stereoselective synthesis of
natural products or for the preparation of other structurally relevant
compounds. The different synthons being put into practice by the use of
lithiated alkoxyallenes in these variations will be discussed.
de
dc.rights.uri
http://creativecommons.org/licenses/by-nc/3.0/
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie
dc.title
Alkoxyallenes as building blocks for organic synthesis
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation
Chem. Soc. Rev. - 43 (2014), 9, S. 2888-2903
dc.identifier.sepid
39590
dcterms.bibliographicCitation.doi
10.1039/C3CS60429B
dcterms.bibliographicCitation.url
http://xlink.rsc.org/?DOI=C3CS60429B
refubium.affiliation
Biologie, Chemie, Pharmazie
de
refubium.funding
OpenAccess Publikation in Allianzlizenz
refubium.mycore.fudocsId
FUDOCS_document_000000021173
refubium.resourceType.isindependentpub
no
refubium.mycore.derivateId
FUDOCS_derivate_000000004068
dcterms.accessRights.openaire
open access