dc.contributor.author
Dommaschk, Marcel
dc.contributor.author
Gutzeit, Florian
dc.contributor.author
Boretius, Susann
dc.contributor.author
Haag, Rainer
dc.contributor.author
Herges, Rainer
dc.date.accessioned
2018-06-08T03:24:56Z
dc.date.available
2014-11-04T09:27:04.009Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/15129
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-19317
dc.description.abstract
We present a non-ionic water-soluble porphyrin that does not exhibit
measurable aggregation even at high concentrations in water. The spin state of
the corresponding nickel(II) complex changes from completely diamagnetic (low-
spin) to paramagnetic (high-spin) upon addition of a strong axial ligand. This
leads to a strongly reduced NMR relaxation time of the water protons even at
low concentrations of the complex.
en
dc.rights.uri
http://creativecommons.org/licenses/by/3.0/
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie
dc.title
Coordination-Induced Spin-State-Switch (CISSS) in water
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation
Chemical Communications. - 50 (2014), 83, S. 12476-12478
dcterms.bibliographicCitation.doi
10.1039/C4CC05525J
dcterms.bibliographicCitation.url
http://dx.doi.org/10.1039/C4CC05525J
refubium.affiliation
Biologie, Chemie, Pharmazie
de
refubium.mycore.fudocsId
FUDOCS_document_000000021228
refubium.resourceType.isindependentpub
no
refubium.mycore.derivateId
FUDOCS_derivate_000000004105
dcterms.accessRights.openaire
open access
