dc.contributor.author
Schiwon, Rafael
dc.contributor.author
Klingan, Katharina
dc.contributor.author
Dau, Holger
dc.contributor.author
Limberg, Christian
dc.date.accessioned
2018-06-08T03:24:46Z
dc.date.available
2015-02-18T11:38:53.649Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/15118
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-19306
dc.description.abstract
Modification of the Co-oxo cores of cobalt-polyoxometalate water oxidation
catalysts is detectable by X-ray absorption spectroscopy (XAS) as demonstrated
by comparison of Na10[Co4(H2O)2(PW9O34)2] (1) and
Na17[((Co(H2O))Co2PW9O34)2(PW6O26)] (2). XAS reveals the integrity of 1
uncompromised by oxidant-driven water oxidation, which proceeds without
formation of catalytic cobalt oxide.
en
dc.rights.uri
http://www.rsc.org/AboutUs/Copyright/Authordeposition.asp
dc.subject.ddc
500 Naturwissenschaften und Mathematik::530 Physik
dc.title
Shining light on integrity of a tetracobalt-polyoxometalate water oxidation
catalyst by X-ray spectroscopy before and after catalysis
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation
Chemical Communications. - 50 (2014), 1, S. 100-102
dc.identifier.sepid
40723
dcterms.bibliographicCitation.doi
10.1039/C3CC46629A
dcterms.bibliographicCitation.url
http://dx.doi.org/10.1039/c3cc46629a
refubium.affiliation
Physik
de
refubium.affiliation.other
Institut für Experimentalphysik
refubium.mycore.fudocsId
FUDOCS_document_000000021870
refubium.resourceType.isindependentpub
no
refubium.mycore.derivateId
FUDOCS_derivate_000000004554
dcterms.accessRights.openaire
open access
dcterms.isPartOf.issn
1359-7345
