dc.contributor.author
Könning, Daniel
dc.contributor.author
Olbrisch, Tobias
dc.contributor.author
Sypaseuth, Fanni D.
dc.contributor.author
Tzschucke, C. Christoph
dc.contributor.author
Christmann, Mathias
dc.date.accessioned
2018-06-08T03:12:46Z
dc.date.available
2014-10-16T08:39:48.808Z
dc.identifier.uri
https://refubium.fu-berlin.de/handle/fub188/14695
dc.identifier.uri
http://dx.doi.org/10.17169/refubium-18885
dc.description.abstract
An oxidation of allylic and benzylic alcohols to the corresponding carboxylic
acids is effected by merging a Cu-catalyzed oxidation using O2 as a terminal
oxidant with a subsequent chlorite oxidation (Lindgren oxidation). The
protocol was optimized to obtain pure products without chromatography or
crystallization. Interception at the aldehyde stage allowed for
Z/E-isomerization, thus rendering the oxidation stereoconvergent with respect
to the configuration of the starting material.
en
dc.rights.uri
http://creativecommons.org/licenses/by/3.0/
dc.subject.ddc
500 Naturwissenschaften und Mathematik::540 Chemie
dc.title
Oxidation of allylic and benzylic alcohols to aldehydes and carboxylic acids
dc.type
Wissenschaftlicher Artikel
dcterms.bibliographicCitation
Chem. Commun. - 50 (2014),39, S. 5014-5016
dc.identifier.sepid
36263
dcterms.bibliographicCitation.doi
10.1039/c4cc01305k
dcterms.bibliographicCitation.url
http://pubs.rsc.org/en/content/articlelanding/2014/cc/c4cc01305k#!divAbstract
refubium.affiliation
Biologie, Chemie, Pharmazie
de
refubium.funding
OpenAccess Publikation in Allianzlizenz
refubium.mycore.fudocsId
FUDOCS_document_000000021155
refubium.resourceType.isindependentpub
no
refubium.mycore.derivateId
FUDOCS_derivate_000000004653
dcterms.accessRights.openaire
open access
dcterms.isPartOf.issn
1359-7345